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High-temperature oxidation of duplex stainless steels
S32101 and
S32304 was performed under three conditions: isothermal oxidation at 1050
°C in air and simulated industrial reheating atmosphere and in situ oxidation in air during the continuous heating to 1050
°C. Breakaway oxidation was found in
S32101 but not in
S32304, before which the weight gain per unit area was in parabolic relation to time. A triplex oxide layer of
S32101 and a duplex-layer of
S32304 oxidized for 120
min were observed, respectively. The initial oxidation phase was austenite for
S32101 and ferrite for
S32304 due to different manganese content.