Angewandte Chemie (International ed.), 2010-08, Vol.49 (33), p.5780-5783
2010
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Details
- Autor(en) / Beteiligte
- Titel
- Rhodium-Catalyzed Asymmetric Conjugate Addition of Organoboronic Acids to Nitroalkenes Using Chiral Bicyclo[3.3.0] Diene Ligands
- Ist Teil von
- Angewandte Chemie (International ed.), 2010-08, Vol.49 (33), p.5780-5783
- Ort / Verlag
- Weinheim: Wiley-VCH Verlag
- Erscheinungsjahr
- 2010
- Quelle
- MEDLINE
- Beschreibungen/Notizen
- Old before I diene: An efficient rhodium/diene‐catalyzed asymmetric conjugate addition of organoboronic acids to challenging nitroalkene substrates that lack α substituents has been developed. Chiral bicyclo[3.3.0] dienes were found to be superior ligands under ArB(OH)2/KHF2 conditions. Np=naphthyl.
- Sprache
- Englisch
- Identifikatoren
- ISSN: 1433-7851eISSN: 1521-3773DOI: 10.1002/anie.201001883Titel-ID: cdi_proquest_miscellaneous_753995301
- Format
- –
- Schlagworte
- Alkenes - chemistry, asymmetric catalysis, Boronic Acids - chemistry, Bridged Bicyclo Compounds - chemistry, Catalysis, conjugate addition, diene ligands, Isoquinolines - chemical synthesis, Isoquinolines - chemistry, Ligands, nitroalkenes, rhodium, Rhodium - chemistry, Stereoisomerism