Details

Autor(en) / Beteiligte

• Fedushkin, Igor L.
• Skatova, Alexandra A.
• Chudakova, Valentina A.
• Fukin, Georgy K.

Titel

Four-Step Reduction of dpp-bian with Sodium Metal: Crystal Structures of the Sodium Salts of the Mono-, Di-, Tri- and Tetraanions of dpp-bian

Ist Teil von

• Angewandte Chemie (International ed.), 2003-07, Vol.42 (28), p.3294-3298

Ort / Verlag

Weinheim: WILEY-VCH Verlag

Erscheinungsjahr

2003

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• One ligand, four anions! Four anionic forms of a single ligand bis[N‐(2,6‐diisopropylphenyl)imino]acenaphthene (dpp‐bian) were isolated on a preparative scale for the first time and unambiguously characterized by single‐crystal X‐ray structure analysis. The ligand, dpp‐bian, may be easily reduced in diethyl ether by sodium metal to give the mono‐, di‐, tri‐, or tetranion (depicted).