Details

Autor(en) / Beteiligte

• Mariott, Wesley R
• Chen, Eugene Y.-X

Titel

Stereochemically Controlled PMMA-Exfoliated Silicate Nanocomposites Using Intergallery-Anchored Metallocenium Cations

Ist Teil von

• Journal of the American Chemical Society, 2003-12, Vol.125 (51), p.15726-15727

Ort / Verlag

Washington, DC: American Chemical Society

Erscheinungsjahr

2003

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Representative C 2 v -, C 2-, and C s -symmetric metallocene complexes were effectively anchored inside the silicate galleries via a non-cation-exchange approach involving protonolysis. These intergallery-anchored metallocenium cations allow for the first synthesis of in situ polymerized nanocomposites comprising exfoliated silicate nanoplatelets homogeneously dispersed in the atactic, isotactic, or syndiotactic PMMA matrixes.