Angewandte Chemie (International ed.), 2003-12, Vol.42 (47), p.5794-5795
2003
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Details
- Autor(en) / Beteiligte
- Titel
- Synthetic Routes towards Enantiomerically Pure β-Amino Acids
- Ist Teil von
- Angewandte Chemie (International ed.), 2003-12, Vol.42 (47), p.5794-5795
- Ort / Verlag
- Weinheim: WILEY-VCH Verlag
- Erscheinungsjahr
- 2003
- Quelle
- MEDLINE
- Beschreibungen/Notizen
- Unusual representatives of the synthetically attractive β‐amino acids can be accessed by two novel synthetic routes. The synthesis of β2,3‐ and β2,3,3‐amino acids (A and B, respectively) involves a diastereoselective 1,3‐dipolar cycloaddition, whereas β2‐amino acids C are obtained by enantioselective CuI‐catalyzed conjugate addition of dialkyl zinc compounds to nitroalkenes.
- Sprache
- Englisch
- Identifikatoren
- ISSN: 1433-7851eISSN: 1521-3773DOI: 10.1002/anie.200301692Titel-ID: cdi_proquest_miscellaneous_71462561
- Format
- –
- Schlagworte
- Alkenes - chemistry, Alkylation, amino acids, Amino Acids - chemical synthesis, Amino Acids - chemistry, Amino Acids - isolation & purification, Copper - chemistry, cycloaddition, diastereoselectivity, enantioselectivity, Michael addition, Molecular Structure, Nitriles - chemistry, Stereoisomerism, Zinc - chemistry