Details

Autor(en) / Beteiligte

• Fedushkin, Igor L.
• Skatova, Alexandra A.
• Ketkov, Sergey Y.
• Eremenko, Olga V.
• Piskunov, Alexander V.
• Fukin, Georgy K.

Titel

[(dpp-bian)ZnZn(dpp-bian)]: A Zinc-Zinc-Bonded Compound Supported by Radical-Anionic Ligands

Ist Teil von

• Angewandte Chemie (International ed.), 2007-06, Vol.46 (23), p.4302-4305

Ort / Verlag

Weinheim: WILEY-VCH Verlag

Erscheinungsjahr

2007

Link zum Volltext

Quelle

MEDLINE

Beschreibungen/Notizen

• Radical help: The use of a spin‐labeled ligand allows a zinc–zinc‐bonded compound supported by radical‐anionic ligands to be prepared (see scheme). The radical anion enabled the presence of the ZnZn bond in solution to be confirmed by ESR spectroscopy. DFT calculations confirm the biradical nature of the compound and indicate that the ZnZn bond is formed mainly by the metal s orbitals.