Details

Autor(en) / Beteiligte

• Hahn, F. Ekkehardt
• Jahnke, Mareike C

Titel

Heterocyclic Carbenes: Synthesis and Coordination Chemistry

Ist Teil von

• Angewandte Chemie (International ed.), 2008-04, Vol.47 (17), p.3122-3172

Ort / Verlag

Weinheim: Wiley-VCH Verlag

Erscheinungsjahr

2008

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• The chemistry of heterocyclic carbenes has experienced a rapid development over the last years. In addition to the imidazolin-2-ylidenes, a large number of cyclic diaminocarbenes with different ring sizes have been described. Aside from diaminocarbenes, P-heterocyclic carbenes, and derivatives with only one, or even no heteroatom within the carbene ring are known. New methods for the synthesis of complexes with N-heterocyclic carbene ligands such as the oxidative addition or the metal atom template controlled cyclization of β-functionalized isocyanides have been developed recently. This review summarizes the new developments regarding the synthesis of N-heterocyclic carbenes and their metal complexes.