Details

Autor(en) / Beteiligte

• Ogoshi, Sensuke
• Arai, Tomoya
• Ohashi, Masato
• Kurosawa, Hideo

Titel

Nickeladihydrofuran. Key intermediate for nickel-catalyzed reaction of alkyne and aldehyde

Ist Teil von

• Chemical communications (Cambridge, England), 2008-03 (11), p.1347-1349

Ort / Verlag

England

Erscheinungsjahr

2008

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• The formation of a nickeladihydrofuran by oxidative cyclization of an alkyne and an aldehyde with nickel(0) has been demonstrated; the transformation of the nickeladihydrofuran into an enone by decomposition, a lactone by carbonylation and an allylic alcohol by treatment with ZnMe(2) suggests that nickeladihydrofuran is an important key intermediate in a variety of catalytic reactions.