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Applications of phosphine-functionalised polymers in organic synthesis
Ist Teil von
Chemical Society reviews, 2007-01, Vol.36 (4), p.608-617
Ort / Verlag
England
Erscheinungsjahr
2007
Quelle
MEDLINE
Beschreibungen/Notizen
This tutorial review deals with recent advances in the use of phosphine-functionalised polymers in organic synthesis. In the first part of the review, some recent applications of polymer-supported palladium catalysts are reviewed, particularly recyclable catalysts for C-C and C-X bond formation with aryl bromide and chloride substrates. In the second half, novel applications of phosphine-functionalised polymers as reagents, scavengers, organocatalysts and linkers in organic chemistry are presented. Emphasis is placed on the synthesis of biologically active molecules.