Angewandte Chemie (International ed.), 2008-09, Vol.47 (40), p.7669-7672
2008
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Details
- Autor(en) / Beteiligte
- Titel
- C₁-Symmetric Monosubstituted Chiral Diene Ligands in Asymmetric Rhodium-Catalyzed 1,4-Addition Reactions
- Ist Teil von
- Angewandte Chemie (International ed.), 2008-09, Vol.47 (40), p.7669-7672
- Ort / Verlag
- Weinheim: Wiley-VCH Verlag
- Erscheinungsjahr
- 2008
- Quelle
- Alma/SFX Local Collection
- Beschreibungen/Notizen
- One trumps two: Monosubstituted chiral bicyclo[2.2.2]octadiene ligands, derived from carvone, form complexes with rhodium to catalyze the asymmetric addition of boronic acid substrates to α,β‐unsaturated ketones (see scheme). The 1,4‐adducts are produced in good yield and high enantioselectivity.
- Sprache
- Englisch
- Identifikatoren
- ISSN: 1433-7851eISSN: 1521-3773DOI: 10.1002/anie.200803230Titel-ID: cdi_proquest_miscellaneous_69621610
- Format
- –
- Schlagworte
- asymmetric synthesis, boron, diene ligands, Michael addition, rhodium