Details

Autor(en) / Beteiligte

• Fedushkin, Igor L.
• Lukoyanov, Anton N.
• Fukin, Georgy K.
• Ketkov, Sergey Yu
• Hummert, Markus
• Schumann, Herbert

Titel

Synthesis, Molecular Structure and DFT Study of [(dpp-bian)GaM(Et2O)3] (M=Li, Na; dpp-bian=1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene)

Ist Teil von

• Chemistry : a European journal, 2008-09, Vol.14 (28), p.8465-8468

Ort / Verlag

Weinheim: WILEY-VCH Verlag

Erscheinungsjahr

2008

Quelle

Access via Wiley Online Library

Beschreibungen/Notizen

• Bonding direct! The compounds [(dpp‐bian)GaM(Et2O)3] (M=Li, and Na; dpp‐bian=1,2‐bis[(2,6‐diisopropylphenyl)imino]acenaphthene) featuring direct metal–gallium bonds, have been prepared by the reduction of [(dpp‐bian)GaGa(dpp‐bian)] with two equivalents of Li or Na, respectively. The calculated GaLi distance of 2.726 Å for the Li complex is in good agreement with the crystal data (structure shown here).