Details

Autor(en) / Beteiligte

• Murahashi, Tetsuro
• Mino, Yukari
• Chiyoda, Koji
• Ogoshi, Sensuke
• Kurosawa, Hideo

Titel

Structures of two haptotropic isomers generated by the sliding of 1,3,5-triene ligands on a Pd-Pd-Pd chain

Ist Teil von

• Chemical communications (Cambridge, England), 2008-09 (34), p.4061-4063

Ort / Verlag

England

Erscheinungsjahr

2008

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Two haptotropic isomers of [Pd3(micro3-DMVC)2(CH3CN)2][BF4]2 (DMVC=1,2-di-(E)-carbomethoxyvinylcyclopentene) were structurally determined by X-ray crystallographic analyses; a monoclinic crystal contained a symmetric sandwich complex (micro3-eta2:eta2:eta2-coordination of DMVC ligands) and a triclinic crystal contained an unsymmetric sandwich complex (micro3-eta2:eta3:eta1-coordination of DMVC ligands), where the latter are connected to each other by C-HO hydrogen bonds.