Details

Autor(en) / Beteiligte

• Murahashi, Tetsuro
• Hashimoto, Yasuhiro
• Chiyoda, Koji
• Fujimoto, Mayu
• Uemura, Tomohito
• Inoue, Ryou
• Ogoshi, Sensuke
• Kurosawa, Hideo

Titel

Reductive Coupling of Metal Triangles in Sandwich Complexes

Ist Teil von

• Journal of the American Chemical Society, 2008-07, Vol.130 (27), p.8586-8587

Ort / Verlag

United States: American Chemical Society

Erscheinungsjahr

2008

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• The one-electron reduction of [Pd3(C7H7)2(CH3CN)3][BF4]2 in acetonitrile resulted in the formation of the dimer dication [Pd6(C7H7)4(CH3CN)4][BF4]2, whose structure containing a novel bitriangle hexapalladium skeleton was determined by X-ray crystallographic analysis. The dimer is stable in CD3CN at ambient temperature for several days but is highly air-sensitive. Similarly, the cycloheptatriene tripalladium complex [Pd3(C7H7R)2(CH3CN)3][BF4]2 (R = H, t-Bu) dimerized upon one-electron reduction. Both monomer and dimer of cycloheptatriene complexes were structurally determined by X-ray crystallographic analyses.