Physical review letters, 2005-12, Vol.95 (24), p.243002.1-243002.4, Article 243002
2005
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Details
- Autor(en) / Beteiligte
- Titel
- Experimental confirmation of quantum monodromy : The millimeter wave spectrum of cyanogen isothiocyanate NCNCS
- Ist Teil von
- Physical review letters, 2005-12, Vol.95 (24), p.243002.1-243002.4, Article 243002
- Ort / Verlag
- Ridge, NY: American Physical Society
- Erscheinungsjahr
- 2005
- Quelle
- PROLA
- Beschreibungen/Notizen
- We have made energy-momentum maps for the experimental end-over-end rotational energy and the two-dimensional bending vibrational energy, both of which confirm the dominating effects of nontrivial quantum monodromy in cyanogen isothiocyanate. Accidental resonances in the rotational spectra yield accurate intervals between bending states.
- Sprache
- Englisch
- Identifikatoren
- ISSN: 0031-9007eISSN: 1079-7114DOI: 10.1103/PhysRevLett.95.243002Titel-ID: cdi_proquest_miscellaneous_69053525
- Format
- –
- Schlagworte
- Atomic and molecular physics, Barrier heights (internal rotation, inversion, rotational isomerism, conformational dynamics), Electronic structure of atoms, molecules and their ions: theory, Exact sciences and technology, Molecular properties and interactions with photons, Molecular spectra, Physics, Potential energy surfaces, Potential energy surfaces for ground electronic states, Properties of molecules and molecular ions, Radio-frequency and microwave spectra