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Top-Down Solid-Phase Fabrication of Nanoporous Cadmium Oxide Architectures
Ist Teil von
Journal of the American Chemical Society, 2007-02, Vol.129 (8), p.2333-2337
Ort / Verlag
United States: American Chemical Society
Erscheinungsjahr
2007
Quelle
MEDLINE
Beschreibungen/Notizen
In this Article, we have demonstrated one-step solid-phase transformation from high-quality cadmium carbonate microcrystals into highly nanoporous cadmium oxide. The high crystal quality of cadmium carbonate is critical for the successful fabrication of porous nanoarchitectures with predetermined morphology and well-controlled internal structure. This novel strategy has a good potential to prepare nanoporous materials at a large scale by using perfect monolithic carbonate crystals, and it is also useful to synthesize different nanoporous materials on metal-oxide-coated substrates. Meanwhile, this simple thermal transformation of cadmium carbonate into porous structures has further been extended to convert calcium carbonate into such porous structures.