Details

Autor(en) / Beteiligte

• Xu, Hong-Bin
• Wang, Bin-Wu
• Pan, Feng
• Wang, Zhe-Ming
• Gao, Song

Titel

Stringing Oxo-Centered Trinuclear [MnIII ₃O] Units into Single-Chain Magnets with Formate or Azide Linkers

Ist Teil von

• Angewandte Chemie (International ed.), 2007-01, Vol.46 (39), p.7388-7392

Ort / Verlag

Weinheim: Wiley-VCH Verlag

Erscheinungsjahr

2007

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Magnetic strings: Single‐molecule‐magnet‐like [Mn3IIIO] units are strung into two chain compounds along the magnetic easy axis with formate and azide anions, respectively, as bridges (see picture). The enhanced uniaxial anisotropy and intrachain coupling of these two chain compounds mean that they act as single‐chain magnets with a high energy barrier for magnetization relaxation.