Angewandte Chemie (International ed.), 2006-05, Vol.45 (22), p.3689-3692
2006
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Details
- Autor(en) / Beteiligte
- Titel
- Highly Enantioselective Aza-Baylis-Hillman Reaction in a Chiral Reaction Medium
- Ist Teil von
- Angewandte Chemie (International ed.), 2006-05, Vol.45 (22), p.3689-3692
- Ort / Verlag
- Weinheim: WILEY-VCH Verlag
- Erscheinungsjahr
- 2006
- Quelle
- Alma/SFX Local Collection
- Beschreibungen/Notizen
- Let's twist again! The first highly enantioselective asymmetric reaction in which a chiral reaction medium is the sole source of chirality is presented. The aza‐Baylis–Hillman reaction in an ionic liquid with a chiral anion, whose design is based on mechanistic insights, gave products with up to 84 % ee.
- Sprache
- Englisch
- Identifikatoren
- ISSN: 1433-7851eISSN: 1521-3773DOI: 10.1002/anie.200600327Titel-ID: cdi_proquest_miscellaneous_67999903
- Format
- –
- Schlagworte
- asymmetric synthesis, C-C coupling, chiral solvents, ionic liquids, organocatalysis