Journal of organic chemistry, 2005-03, Vol.70 (6), p.2322-2324
2005
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Details
- Autor(en) / Beteiligte
- Titel
- Heterocyclic Rearrangements in Constrained Media. A Zeolite-Directed Photorearrangement of 1,2,4-Oxadiazoles
- Ist Teil von
- Journal of organic chemistry, 2005-03, Vol.70 (6), p.2322-2324
- Ort / Verlag
- Washington, DC: American Chemical Society
- Erscheinungsjahr
- 2005
- Quelle
- MEDLINE
- Beschreibungen/Notizen
- The first intrazeolite-photoinduced rearrangement of a five-membered heterocycle is reported. A completely different behavior compared to solution irradiations has been observed. The zeolite's role in directing the photoreaction of 3-phenyl-1,2,4-oxadiazoles toward the formation of the corresponding 1,3,4-oxadiazoles in a ring contraction − ring expansion route is discussed.
- Sprache
- Englisch
- Identifikatoren
- ISSN: 0022-3263eISSN: 1520-6904DOI: 10.1021/jo047910+Titel-ID: cdi_proquest_miscellaneous_67507971
- Format
- –
- Schlagworte
- Chemistry, Cyclization, Exact sciences and technology, General and physical chemistry, Heterocyclic compounds, Heterocyclic compounds with n hetero atom and also o and/or s, se, te hetero atoms, Models, Molecular, Molecular Structure, Organic chemistry, Oxadiazoles - chemical synthesis, Oxadiazoles - radiation effects, Photochemistry, Physical chemistry of induced reactions (with radiations, particles and ultrasonics), Preparations and properties, Ultraviolet Rays, Zeolites - chemistry