Details

Autor(en) / Beteiligte

• Cui, Hai-Lei
• Feng, Xin
• Peng, Jing
• Lei, Jie
• Jiang, Kun
• Chen, Ying-Chun

Titel

Chemoselective Asymmetric N-Allylic Alkylation of Indoles with Morita-Baylis-Hillman Carbonates

Ist Teil von

• Angewandte Chemie (International ed.), 2009-01, Vol.48 (31), p.5737-5740

Ort / Verlag

Weinheim: Wiley-VCH Verlag

Erscheinungsjahr

2009

Quelle

MEDLINE

Beschreibungen/Notizen

• Give me convenience: The title transformation has been developed by employing metal‐free catalysis of modified cinchona alkaloids. Moderate to excellent enantioselectivities have been achieved for a broad array of substrates (see scheme). This reaction also provides a convenient method to prepare multiply functionalized pyrrolo[1,2‐a]indole and pyrrolo[3,2,1‐ij]quinoline derivatives.