Details

Autor(en) / Beteiligte

• Fantasia, Serena
• Egbert, Jonathan D
• Jurčík, Václav
• Cazin, Catherine S.J
• Jacobsen, Heiko
• Cavallo, Luigi
• Heinekey, D. Michael
• Nolan, Steven P

Titel

Activation of Hydrogen by Palladium(0): Formation of the Mononuclear Dihydride Complex trans-[Pd(H)₂(IPr)(PCy₃)]

Ist Teil von

• Angewandte Chemie (International ed.), 2009-01, Vol.48 (28), p.5182-5186

Ort / Verlag

Weinheim: Wiley-VCH Verlag

Erscheinungsjahr

2009

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• An even split: In sharp contrast with the general behavior of Pd⁰ complexes, [Pd(IPr)(PCy₃)] is able to activate the H---H bond. The resulting trans-[Pd(H)₂(IPr)(PCy₃)] is the first isolated mononuclear dihydride palladium compound. Its formation is supported by multinuclear NMR spectroscopy, density functional calculations, and X-ray diffraction studies. The stability and reactivity of this new species are examined.