Details

Autor(en) / Beteiligte

• Viciano, Mónica
• Mas-Marzá, Elena
• Poyatos, Macarena
• Sanaú, Mercedes
• Crabtree, Robert H.
• Peris, Eduardo

Titel

An N-Heterocyclic Carbene/Iridium Hydride Complex from the Oxidative Addition of a Ferrocenyl-Bisimidazolium Salt: Implications for Synthesis

Ist Teil von

• Angewandte Chemie (International ed.), 2005-01, Vol.44 (3), p.444-447

Ort / Verlag

Weinheim: WILEY-VCH Verlag

Erscheinungsjahr

2005

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• A ferrocenyl–imidazolium salt can be employed as a precursor to a stable [IrIII(H)(biscarbene)] complex (see X‐ray crystal structure) under very mild conditions. The study shows that the role of the base in the activation of the imidazolium salt may not just be a simple deprotonation of the precursor.