Details

Autor(en) / Beteiligte

• Xu, Dan‐Qian
• Xia, Ai‐Bao
• Luo, Shu‐Ping
• Tang, Jie
• Zhang, Shuai
• Jiang, Jun‐Rong
• Xu, Zhen‐Yuan

Titel

In Situ Enamine Activation in Aqueous Salt Solutions: Highly Efficient Asymmetric Organocatalytic Diels–Alder Reaction of Cyclohexenones with Nitroolefins

Ist Teil von

• Angewandte Chemie International Edition, 2009-05, Vol.48 (21), p.3821-3824

Ort / Verlag

Weinheim: WILEY‐VCH Verlag

Erscheinungsjahr

2009

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Deep‐sea Diels–Alder: The asymmetric organocatalytic Diels–Alder reaction of cyclohexenones with aromatic nitroolefins can be carried out in seawater and brine. The reaction proceeds by an in situ enamine activation involving a one‐step concerted addition pathway (see scheme). Deep‐sea Diels–Alder: The asymmetric organocatalytic Diels–Alder reaction of cyclohexenones with aromatic nitroolefins can be carried out in seawater and brine. The reaction proceeds by an in situ enamine activation involving a one‐step concerted addition pathway (see scheme).