Details

Autor(en) / Beteiligte

• Wang, Jingping
• Zhao, Junwei
• Ma, Pengtao
• Ma, Junchuang
• Yang, Linping
• Bai, Yan
• Li, Mingxue
• Niu, Jingyang

Titel

A novel type of heteropolyoxoanion precursors [[Ca(H2O)]6[P4M6O34]2](12-) (M = WVI, MoVI) constructed by two [P4M6O34](12-) subunits via a rare hexa-calcium cluster

Ist Teil von

• Chemical communications (Cambridge, England), 2009-05 (17), p.2362-2364

Ort / Verlag

England

Erscheinungsjahr

2009

Link zum Volltext

Quelle

MEDLINE

Beschreibungen/Notizen

• A novel type of heteropolyoxoanion (HPOA) precursors [[Ca (H(2)O)](6)[P(4)M(6)O(34)](2)](12-) [M = W(VI) (1), Mo(VI) (2)] has been synthesized and structurally characterized, which represents the rare membership of the HPOA family constituted by two early-transition-metal clusters ([P(4)M(6)O(34)](12-)) and a main-group metal cluster of high nuclearity ([Ca(6)](12+)).