Details

Autor(en) / Beteiligte

• Yoon, Jihae
• Wilson, Samuel A
• Jang, Yu Kyeong
• Seo, Mi Sook
• Nehru, Kasi
• Hedman, Britt
• Hodgson, Keith O
• Bill, Eckhard
• Solomon, Edward I
• Nam, Wonwoo

Titel

Reactive Intermediates in Oxygenation Reactions with Mononuclear Nonheme Iron Catalysts

Ist Teil von

• Angewandte Chemie (International ed.), 2009-02, Vol.48 (7), p.1257-1260

Ort / Verlag

Weinheim: Wiley-VCH Verlag

Erscheinungsjahr

2009

Quelle

MEDLINE

Beschreibungen/Notizen

• An advanced intermediate: A nonheme iron(IV) oxo complex [FeIV(O)(bqen)(L)]n⁺ (bqen=N,N'-dimethyl-N,N'-bis(8-quinolyl)ethane-1,2-diamine, L=CH₃CN or CF₃SO₃ ⁻) activates the C---H bonds of alkanes and alcohols by a hydrogen-atom abstraction mechanism. The catalytic oxidation of these species is proposed to occur through a nonheme iron(V) oxo species, with a high reactivity in oxidation reactions (see picture).