Journal of the American Chemical Society, 2004-09, Vol.126 (35), p.10862-10863
2004
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Details
- Autor(en) / Beteiligte
- Titel
- Highly Diastereoselective and Enantioselective C−H Functionalization of 1,2-Dihydronaphthalenes: A Combined C−H Activation/Cope Rearrangement Followed by a Retro-Cope Rearrangement
- Ist Teil von
- Journal of the American Chemical Society, 2004-09, Vol.126 (35), p.10862-10863
- Ort / Verlag
- Washington, DC: American Chemical Society
- Erscheinungsjahr
- 2004
- Quelle
- Alma/SFX Local Collection
- Beschreibungen/Notizen
- The Rh2(S-DOSP)4-catalyzed reaction of vinyldiazoacetates with dihydronaphthalenes results in a highly enantioselective (91−99.6% ee) and diastereoselective (>98% de) C−H functionalization. The apparent intermolecular C−H insertion was demonstrated to be a combined C−H activation/Cope rearrangement followed by a retro-Cope rearrangement.
- Sprache
- Englisch
- Identifikatoren
- ISSN: 0002-7863eISSN: 1520-5126DOI: 10.1021/ja047185kTitel-ID: cdi_proquest_miscellaneous_66830611
- Format
- –
- Schlagworte
- Chemical reactivity, Chemistry, Exact sciences and technology, Organic chemistry, Reactivity and mechanisms