Details

Autor(en) / Beteiligte

• Braunschweig, Holger
• Forster, Melanie
• Seeler, Fabian

Titel

Synthesis and Structure of Heterodinuclear Rhodium and Iridium Borylene Complexes

Ist Teil von

• Chemistry : a European journal, 2009-01, Vol.15 (2), p.469-473

Ort / Verlag

Weinheim: WILEY-VCH Verlag

Erscheinungsjahr

2009

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Herein we report on the synthesis and structural characterization of a representative range of novel heterodinuclear bridging rhodium and iridium borylene complexes. The iridium borylene complexes feature an unusual coordination mode of the borylene ligand. Furthermore, the first instance of a heterodinuclear‐bridged borylene compound containing a chromium atom in the three‐membered ring is reported. Photochemically induced borylene transfer to [(η5‐C5R5)M(CO)2] (M=Rh, R=H; M=Ir, R=Me) from [(OC)5MBN(SiMe3)2] (M=Cr, W) generates the first instances of heterodinuclear bridged rhodium and iridium borylene complexes. The iridium borylene complexes feature an unprecedented coordination mode of the borylene ligand (see picture) . Furthermore, the first heterodinuclear bridged borylene compound containing a chromium atom in the three‐membered ring is presented.