Magnetic resonance in chemistry, 2004-07, Vol.42 (7), p.589-593
2004
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Details
- Autor(en) / Beteiligte
- Titel
- Solution structure of the palladium(II) complex of 1,4,7,10-tetrathiacyclododec-2-ene-2,3-dicarbonitrile
- Ist Teil von
- Magnetic resonance in chemistry, 2004-07, Vol.42 (7), p.589-593
- Ort / Verlag
- Chichester, UK: John Wiley & Sons, Ltd
- Erscheinungsjahr
- 2004
- Quelle
- MEDLINE
- Beschreibungen/Notizen
- The solution structure of the Pd(II) complex of mn‐12‐S4 was studied in detail by NMR spectroscopy. The stoichiometry of the complex was determined by 1H NMR titration experiments. 3J(H,H) coupling constants were extracted from the 2D J‐resolved NMR spectrum of the complex providing information concerning the S—C—C—S torsional angles. Further conclusions about the conformation of [Pd(mn‐12‐S4)](BF4)2 were drawn from experimental NOEs. The results of the NMR study were corroborated by molecular modelling. Copyright © 2004 John Wiley & Sons, Ltd.
- Sprache
- Englisch
- Identifikatoren
- ISSN: 0749-1581eISSN: 1097-458XDOI: 10.1002/mrc.1378Titel-ID: cdi_proquest_miscellaneous_66673429
- Format
- –
- Schlagworte
- 13C NMR, 1H NMR, Algorithms, Carbon Isotopes, H coupling constants, Hydrogen Bonding, Magnetic Resonance Spectroscopy - methods, maleonitrile tetrathia crown ether, Models, Chemical, Models, Molecular, Molecular Conformation, molecular modelling, Motion, Nitriles - analysis, Nitriles - chemistry, NMR, NOE, Palladium - analysis, Palladium - chemistry, Pd(II) complex, preferred conformation, Protons, Solutions, Sulfur Compounds - analysis, Sulfur Compounds - chemistry, vicinal H, vicinal H,H coupling constants