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Phosphorescence of the π-conjugated Polymers with Complex Forming C60 Fullerenes During Irradiation
Ist Teil von
Fullerenes, nanotubes, and carbon nanostructures, 2008-09, Vol.16 (5-6), p.622-628
Ort / Verlag
Taylor & Francis Group, LLC
Erscheinungsjahr
2008
Quelle
Alma/SFX Local Collection
Beschreibungen/Notizen
The photoluminescence spectra and the optical conductivity of the precipitated films of the pure organic molecular PVK polymers and their nanocomposites containing C
60
fullerenes with the concentration from 0,5 to 3wt% were studied. The photoluminescence spectra for the composites containing considerable amount of fullerenes irradiated with the 140 keV copper ions and the dose 4,2
.
10
14
ion/cm
2
also were investigated. It is shown that the formation of both the intermolecular complexes causing changes of the spectra of photoluminescence and interband electron transitions in the nanocomposites takes place. The ionic implantation with copper leads to the creation of the metallic centers that influences on the formation of new channels of the radiationless recombination and transport of the photogenerated electron-hole pairs.