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The purpose of this work was to develop a method for predicting temperature dependent viscosities of biodiesel based on fatty acid ester composition. The Grunberg–Nissan equation combined with a group contribution method was used as the mixing rule to calculate viscosities of mixtures of fatty acid esters. Prediction errors at 25
°C were less than 2.5% for 22 mixtures of fatty acid ethyl esters. Compared with experimentally measured viscosities at 20–100
°C, predicted viscosities of soybean oil and yellow grease methyl esters were within 3%. For coconut, palm and canola oil methyl esters, maximum errors were underestimations at approximately 7%.