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Polymer supported reagents have become the subject of considerable and increasing interest as insoluble materials in the organic synthesis. The attachment of the reagents to the insoluble macromolecular matrix can solve the problems of tedious work-up, lability, toxicity, or unrecyclability often experienced with non-polymeric low-molecular weight reagents. A literature survey shows that a review on poly(vinylpyridine)-supported reagents is not available yet. This review will focus on the implementation of methodologies for polymer supported reagents based on poly(vinylpyridine) (PVPy), in the organic synthesis appeared in the literature until the year of 2009. The aim is to distill the literature into three categories and to present each as a short table listing the functionalized polymers involved, along with their relevant applications as reagents. In the text, discussions on the structural and transformation of some typical polymeric reagents are given, although there is not detailed procedure provided in the text about the synthesis of the polymers or their transformations. When appropriate, comparison between the behaviour of supported reagents versus non-supported reagents is attempted. This review does not include the patent literature.
Sprache
Englisch
Identifikatoren
ISSN: 1026-1265
Titel-ID: cdi_proquest_miscellaneous_33820412
Format
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Weiterführende Literatur
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