Details

Autor(en) / Beteiligte

• Feng, Qin-Zhong
• Zhao, Li-Xia
• Yan, Wei
• Ji, Feng
• Wei, Yan-Lin
• Lin, Jin-Ming

Titel

Molecularly imprinted solid-phase extraction and flow-injection chemiluminescence for trace analysis of 2,4-dichlorophenol in water samples

Ist Teil von

• Analytical and bioanalytical chemistry, 2008-06, Vol.391 (3), p.1073-1079

Ort / Verlag

Berlin/Heidelberg: Berlin/Heidelberg : Springer-Verlag

Erscheinungsjahr

2008

Quelle

MEDLINE

Beschreibungen/Notizen

• Highly sensitive flow-injection chemiluminescence (CL) combined with molecularly imprinted solid-phase extraction (MISPE) has been used for determination of 2,4-dichlorophenol (2,4-DCP) in water samples. The molecularly imprinted polymer (MIP) for 2,4-DCP was prepared by non-covalent molecular imprinting methods, using 4-vinylpyridine (4-VP) and ethylene glycol dimethacrylate (EGDMA) as the monomer and cross-linker, respectively. 2,4-DCP could be selectively adsorbed by the MIP and the adsorbed 2,4-DCP was determined by its enhancing effect on the weak chemiluminescence reaction between potassium permanganate and luminol. The enhanced CL intensity was linear in the range from 1 x 10⁻⁷ to 2 x 10⁻⁵g mL⁻¹. The LOD (S/N = 3) was 1.8 x 10⁻⁸g mL⁻¹, and the relative standard deviation (RSD) was 3.0% (n = 11) for 1.4 x 10⁻⁶g mL⁻¹. The proposed method had been successfully applied to the determination of 2,4-DCP in river water. [graphic removed]