Details

Autor(en) / Beteiligte

• Zhu, Ying
• Li, Jiuming
• Wan, Meixiang
• Jiang, Lei

Titel

3D-boxlike polyaniline microstructures with super-hydrophobic and high-crystalline properties

Ist Teil von

• Polymer (Guilford), 2008-07, Vol.49 (16), p.3419-3423

Ort / Verlag

Oxford: Elsevier Ltd

Erscheinungsjahr

2008

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Three-dimensional boxlike microstructures assembled from 1D-nanofibers of polyaniline (PANI) were synthesized by a template-free method in the presence of perfluorosebacic acid (PFSEA) as the dopant for the first time. The 3D-boxlike microstructures show both super-hydrophobic and high-crystalline properties. The trick of forming such complex micro/nanostructures is that the PFSEA not only serves as both dopant and soft-template, but also provides hydrogen bond and hydrophobic interactions as driving forces for self-assembly from 1D-nanofibers to 3D-boxlike microstructures due to low-surface energy perfluorinated carbon chain and two hydrophilic –COOH end groups. [Display omitted]