Details

Autor(en) / Beteiligte

• Eguchi, Shiori
• Naoe, Mami
• Kageyama, Asako
• Imai, Yoshitane
• Tohnai, Norimitsu
• Yamazaki, Shoko
• Nakata, Eiji
• Takashima, Hiroshi

Titel

Circularly polarised luminescence from intramolecular excimer emission of bis-1,8-naphthalimide derivatives

Ist Teil von

• Organic & biomolecular chemistry, 2024-05

Ort / Verlag

England

Erscheinungsjahr

2024

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Chiral excimers exhibit unique photophysical behaviour. However, further molecular design is required along with systematic studies on the effect of spacer groups and solvent polarity. In this study, we prepared four circularly polarised luminescence (CPL)-active molecules that exhibit intramolecular excimer emission. Bis-1,8-naphthalimide (bNI) derivatives D-LybNI, L-LybNI, D-LyMebNI, and L-LyMebNI were prepared with chiral backbones and alkyl linkages between the NI rings with chain lengths of five carbon atoms, suitable for excimer fluorescence. The fluorescence properties were investigated experimentally and theoretically using density functional theory. The molecules exhibited intramolecular excimer fluorescence in polar organic solvents. Mirror-image circular dichroism and CPL spectra were obtained for the D and L forms. D- and L-LyMebNI exhibited relatively large luminescence dissymmetry factors (| |) in acetonitrile of 1.9 × 10 and 1.6 × 10 , respectively. Thus, this study demonstrates chiral bNI derivatives with simple synthesis procedures that emit intramolecular excimer fluorescence and have effective CPL properties. These molecules are promising for developing organic molecular systems with bright, highly polarised emission.