Details

Autor(en) / Beteiligte

• Zayakin, Igor A.
• Petunin, Pavel V.
• Postnikov, Pavel S.
• Dmitriev, Alexey A.
• Gritsan, Nina P.
• Dorovatovskii, Pavel
• Korlyukov, Alexander
• Fedin, Matvey V.
• Bogomyakov, Artem S.
• Akyeva, Anna Ya
• Novikov, Roman A.
• Shangin, Pavel G.
• Syroeshkin, Mikhail A.
• Burykina, Julia V.
• Tretyakov, Evgeny V.

Titel

Toward New Horizons in Verdazyl-Nitroxide High-Spin Systems: Thermally Robust Tetraradical with Quintet Ground State

Ist Teil von

• Journal of the American Chemical Society, 2024-05, Vol.146 (19), p.13666-13675

Ort / Verlag

United States: American Chemical Society

Erscheinungsjahr

2024

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• High-spin organic tetraradicals with significant intramolecular exchange interactions have high potential for advanced technological applications and fundamental research, but examples reported to date exhibit limited stability and processability. In this work, we designed the first tetraradical based on an oxoverdazyl core and nitronyl nitroxide radicals and successfully synthesized it using a palladium-catalyzed cross-coupling reaction of an oxoverdazyl radical bearing three iodo-phenylene moieties with a gold­(I) nitronyl nitroxide-2-ide complex in the presence of a recently developed efficient catalytic system. The molecular and crystal structures of the tetraradical were confirmed by single crystal X-ray diffraction analysis. The tetraradical possesses good thermal stability with decomposition onset at ∼125 °C in an inert atmosphere; in a toluene solution upon prolonged heating at 90 °C in air, no decomposition was observed. The resulting unique verdazyl-nitroxide conjugate was thoroughly studied using a range of experimental and theoretical techniques, such as SQUID magnetometry of polycrystalline powders, EPR spectroscopy in various matrices, cyclic voltammetry, and high-level quantum chemical calculations. All collected data confirm the high thermal stability of the resulting tetraradical and quintet multiplicity of its ground state, which makes the synthesis of this important paramagnet a new milestone in the field of creating high-spin systems.