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Temperature dependence of the linear birefringence Δn and excess entropy ΔS in a phase transitions regions are presented for the (CH
3
NH
3
)
5
Bi
2
Cl
11
and (CH
3
NH
3
)
5
Bi
2
Br
11
ferroelectric crystals. We have confirmed that there is a linear relation between Δn and ΔS in the temperature range from 285 to 306 K and from 295 to 306 K for (CH
3
NH
3
)
5
Bi
2
Cl
11
and (CH
3
NH
3
)
5
Bi
2
Br
11
crystals, respectively. Our results imply that relation between the linear birefringence and excess entropy can be described by Landau theory.