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Activities of aqueous Na + and Cl - ions from homoionic measurements with null junction potentials at different concentrations
Ist Teil von
Chemical engineering science, 2007-07, Vol.62 (14), p.3849-3857
Ort / Verlag
Oxford: Elsevier Ltd
Erscheinungsjahr
2007
Quelle
Elsevier ScienceDirect Journals
Beschreibungen/Notizen
Individual
Na
+
and
Cl
-
ionic activity coefficients were measured in aqueous solutions of NaCl at 298.15
K in a homoionic system. The emf of sodium and chloride half-cell ion-selective electrodes (ISEs) was measured against a single junction reference electrode of Ag/AgCl, filled with NaCl solutions. Experimental runs were performed at concentrations 0.5, 1.0, 1.5, 2.0, 2.5 and 3.0
m of the filling solution. In each run, the concentration of the sample solution was increased from around
1
×
10
-
3
m
, up to the corresponding molality of the filling solution. Thus, the last point of each run had a zero liquid-junction potential. The ionic activity coefficients measured in this work were found to be independent of the molal concentration of the filling solution used and in good agreement with previous results obtained using heteroionic systems.