Details

Autor(en) / Beteiligte

• Xue, Dongfeng
• Zuo, Sen
• Ratajczak, Henryk

Titel

Electronegativity and structural characteristics of lanthanides

Ist Teil von

• Physica. B, Condensed matter, 2004-10, Vol.352 (1-4), p.99-104

Ort / Verlag

Amsterdam: Elsevier B.V

Erscheinungsjahr

2004

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• On the basis of crystallographic structures of over 1000 lanthanide complexes, the electronegativity of lanthanides and lanthanide–oygen bond length are quantitatively calculated by the bond valence model. Some relationships among the electronegativity, bond length, lanthanide atomic number and lanthanide coordination number in various lanthanide metal-organic complexes are found in this work. The electronegativity decreases with an increase in the lanthanide coordination number and increases with an increase in the lanthanide atomic number. The lanthanide–oxygen bond length decreases with an increase in the lanthanide atomic number and increases with an increase in the lanthanide coordination number.