Details

Autor(en) / Beteiligte

• Kapper, Savannah C
• Ponnekanti, Aamani
• Schaab, Jonas
• Tian-Yi, Li
• Chung, Christine L
• Ung, Gaël
• Djurovich, Peter I
• Thompson, Mark E

Titel

Bis-oxazoline derivatives as ancillary ligands for bis-cyclometalated iridium complexes

Ist Teil von

• Journal of organometallic chemistry, 2024-01, Vol.1004, p.122947, Article 122947

Ort / Verlag

Switzerland

Erscheinungsjahr

2024

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Organometallic iridium complexes with two cyclometalated ligands (ĈN) and one bis-oxazoline derived ancillary ligand (L^X), . (ĈN) Ir(L^X), are reported. The ĈN ligands are 1-phenylpyrazoline (ppz), 2-(4,6-difluorophenyl)pyridine (F ppy), 2-phenylpyridine (ppy), 1-phenylisoquinoline (piq). The box ligand is (4S)-(+)-phenyl-α-[(4S)-phenyloxazolidin-2-ylidene]-2-oxazoline-2-acetonitrile. The emission of these complexes span across the visible and into the near-ultraviolet region of the electromagnetic spectrum with moderate to high photoluminescence quantum yields (Φ = 0.45-1.0). These complexes were found to emit from a metal-ligand to ligand charge transfer (ML'LCT) state and have lifetimes (1.3-2.1 μs), radiative rates (10 s ), and nonradiative rates (10 -10 s ) comparable to state-of-the-art iridium emitters. The (ppy) Ir(BOX-CN) complexes were resolved into the Δ- and Λ- diastereomers using differences in their solubility and additionally characterized by x-ray crystallography, stability, and chiroptic studies. The high Φ of these isomers results in the best to date brightness for circularly polarized luminescence (CPL) from iridium complexes (7.0 M cm ), with dissymmetry factors of -0.57 × 10 and +1.9 × 10 for and , respectively. The significant difference in CPL magnitude between and likely arises from interligand interactions (edge-to-face arrangement versus strong π-π interaction) for the pendant phenyl ring of the BOX-CN ligand which differ for the two isomers.