Details

Autor(en) / Beteiligte

• Wang, Yan
• Wu, Guangming
• Yan, Kaiyu
• Qin, Jiaheng
• Liu, Rui
• Rong, Nannan
• Tang, Yongming
• Loh, Teck-Peng
• Xie, Peizhong

Titel

Sulfination of Unactivated Allylic Alcohols via Sulfinate–Sulfone Rearrangement

Ist Teil von

• Organic letters, 2023-12, Vol.25 (49), p.8895-8900

Ort / Verlag

United States: American Chemical Society

Erscheinungsjahr

2023

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• A dehydrative cross-coupling of unactivated allylic alcohols with sulfinic acids was achieved under catalyst-free conditions. This reaction proceeded via allyl sulfination and concomitant allyl sulfinate–sulfone rearrangement. Various allylic sulfones could be obtained in good to excellent yields with water as the only byproduct. This study expands the synthetic toolbox for constructing allylic sulfone molecules.