Details

Autor(en) / Beteiligte

• Sakamoto, Aiko
• Ogata, Daisuke
• Shikata, Toshiyuki
• Urakawa, Osamu
• Hanabusa, Kenji

Titel

Large macro-dipoles generated in a supramolecular polymer of N, N′, N″-tris(3,7-dimethyloctyl)benzene-1,3,5-tricarboxamide in n-decane

Ist Teil von

• Polymer (Guilford), 2006-02, Vol.47 (4), p.956-960

Ort / Verlag

Oxford: Elsevier Ltd

Erscheinungsjahr

2006

Quelle

ScienceDirect

Beschreibungen/Notizen

• A supramolecular polymer formed by N, N′, N″-tris(3,7-dimethyloctyl)benzene-1,3,5-tricarboxamide (DO 3B) in n-decane (C 10) possesses large macro-dipoles naturally generated by three-fold inter-molecular hydrogen bonding aligned along its helical columnar structure connected by defective portions, which are DO 3B molecules containing failure in the hydrogen bond formation, in the order of head to tail arrangement without dipole inversion like type-A polymers.