Details

Autor(en) / Beteiligte

• Gonzalez, Andres
• Demeshko, Serhiy
• Meyer, Franc
• Werncke, C. Gunnar

Titel

A low-coordinate iron organoazide complex

Ist Teil von

• Chemical communications (Cambridge, England), 2023-09, Vol.59 (77), p.11532-11535

Ort / Verlag

Cambridge: Royal Society of Chemistry

Erscheinungsjahr

2023

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• A labile organoazide iron complex is reported. Under ambient conditions, the azide adduct is subject to a dissociation equilibrium in solution, yet also undergoes intramolecular C-H bond amination. Single-crystal irradiation of the azide at 80 K leads to partial N 2 -extrusion and formation of a putative imido iron intermediate, which was computationally identified as a highly covalent {FeNR} 8 species. The isolation and behaviour of a labile iron organoazide adduct is reported.