Details

Autor(en) / Beteiligte

• Benz, Maximilian
• Dörrich, Sabrina
• Klapötke, Thomas M.
• Lenz, Tobias
• Mouzayek, Mohamed
• Stierstorfer, Jörg

Titel

4,5-Bisnitratomethyl and Similar Representatives of the Rare Class of 2‑Nitro-1,2,3-triazoles

Ist Teil von

• Organic letters, 2023-08, Vol.25 (32), p.5974-5977

Ort / Verlag

United States: American Chemical Society

Erscheinungsjahr

2023

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• A [3+2]-cycloaddition toward bishydroxymethyl-1,2,3-triazole makes the title compound available through selective nitration. The obtained sensitive 2-nitrotriazole was shown to have a high density of 1.764 g cm–3 and a detonation velocity of 8590 m s–1. It can also be classified as an oxidizer with an oxygen balance toward CO of 12%. Further representatives of this rare class of 2-nitro-1,2,3-triazoles were synthesized. One- and two-dimensional 15N NMR spectroscopy, crystal structure, and elemental analysis were performed.