Details

Autor(en) / Beteiligte

• Miao, Yu-Hang
• Hua, Yuan-Zhao
• Jia, Shi-Kun
• Xiao, Xiao
• Wang, Min-Can
• Mei, Guang-Jian

Titel

Zn-ProPhenol catalyzed asymmetric inverse-electron-demand Diels-Alder reaction

Ist Teil von

• Chemical communications (Cambridge, England), 2023-06, Vol.59 (45), p.6929-6932

Ort / Verlag

England: Royal Society of Chemistry

Erscheinungsjahr

2023

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• The first Zn-ProPhenol catalyzed asymmetric inverse-electron-demand Diels-Alder reaction has been accomplished. This protocol was carried out by a dual-activation mode under mild conditions, allowing the preparation of various biologically important dihydropyrans in good yields with excellent stereoselectivities. The first Zn-ProPhenol catalyzed asymmetric inverse-electron-demand Diels-Alder reaction of β,γ-unsaturated α-ketoamides with β,γ-unsaturated ketones has been accomplished.