Details

Autor(en) / Beteiligte

• Dumeignil, Franck
• Sato, Koichi
• Imamura, Motoyasu
• Matsubayashi, Nobuyuki
• Payen, Edmond
• Shimada, Hiromichi

Titel

Modification of structural and acidic properties of sol–gel-prepared alumina powders by changing the hydrolysis ratio

Ist Teil von

• Applied catalysis. A, General, 2003-02, Vol.241 (1), p.319-329

Ort / Verlag

Amsterdam: Elsevier B.V

Erscheinungsjahr

2003

Link zum Volltext

Quelle

Elsevier ScienceDirect Journals Complete

Beschreibungen/Notizen

• The structural and acidic properties of sol–gel prepared alumina powders as catalyst supports were modified by adjusting the hydrolysis ratio, R (i.e. molar ratio of water relative to the alumina precursor, R=[H 2O]/[aluminium-tri-sec-butoxide (ASB)]). Structural properties (e.g. porosity) and acidic properties were measured for alumina powders prepared with various R values, from 3 to 13. For R<9 and R>10, first-order particles were closely packed with ink-bottle-type pore structures, whereas for R=9 or 10, first-order particles were loosely packed with a spatial fractal arrangement that yielded pseudo-cylindrical pore structures. In addition, the alumina powders prepared with R=9 or 10 had larger water pore volume and stronger acidity than those with other R values. These properties unique to the powders prepared with R=9 or 10 were ascribed to relatively short Al–O–Al chain lengths that resulted in loose packing of first-order particles. The results here indicate that alumina powders with favorable properties as catalyst supports (e.g. mean pore diameter) can be tailored by selecting the appropriate R in the sol–gel synthesis process.