Details

Autor(en) / Beteiligte

• Li, Lulu
• Deng, Zhiming
• Chen, Mengjie
• Yu, Zhong-Zhen
• Russell, Thomas P.
• Zhang, Hao-Bin

Titel

3D Printing of Ultralow-Concentration 2D Nanomaterial Inks for Multifunctional Architectures

Ist Teil von

• Nano letters, 2023-01, Vol.23 (1), p.155-162

Ort / Verlag

United States: American Chemical Society

Erscheinungsjahr

2023

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• The direct 3D printing of ultralight architectures with ultralow-concentration 2D nanomaterial inks is necessary yet challenging. Here, we describe an emulsion-based ink for direct printing using 2D nanomaterials, i.e., MXene and graphene oxide (GO). The electrostatic interactions between the ligands in the oil phase and the 2D nanomaterials in the aqueous phase help form sheet-like surfactants at the interface. The interactions between the anchored ligands among different droplets dictate the rheological characteristics of inks, enabling a gel-like behavior ideally suitable for 3D printing at ultralow concentrations of 2D nanomaterials. The 3D printed foams possess lightweight structures with densities of 2.8 mg cm–3 (GO-based) and 4.1 mg cm–3 (MXene-based), and the latter integrates outstanding electrical conductivity, electromagnetic shielding performance, and thermal insulation comparable to air. This work describes a general approach for direct-printing ultralight porous structures that take advantage of the inherent properties of 2D building blocks.