Electrochimica acta, 1997, Vol.42 (13), p.2233-2239
1997
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Details
- Autor(en) / Beteiligte
- Titel
- Stereoselective homocoupling of phenylacetic acid derivatives utilizing electrochemically generated base
- Ist Teil von
- Electrochimica acta, 1997, Vol.42 (13), p.2233-2239
- Ort / Verlag
- Elsevier Ltd
- Erscheinungsjahr
- 1997
- Quelle
- Elsevier Journal Backfiles on ScienceDirect (DFG Nationallizenzen)
- Beschreibungen/Notizen
- Electrochemically generated base (EGB) was cathodically prepared from pyrrolidone, and it was used as an efficient base to generate an anion of methyl phenylacetate. The anion was oxidized by iodine to afford dimethyl 2, 3-diphenylsuccinate in high yield and high dl selectivity. Optically active 2, 3-diphenylsuccinic acid derivative was prepared by this EGB/iodine method. The oxidative homocoupling of methyl phenylacetate was also achieved with a catalytic amount of iodine by utilizing an electrochemical mediator system.
- Sprache
- Englisch
- Identifikatoren
- ISSN: 0013-4686eISSN: 1873-3859DOI: 10.1016/S0013-4686(97)85504-1Titel-ID: cdi_proquest_miscellaneous_27373393
- Format
- –
- Schlagworte
- 3-diphenylsuccinic acid, C 2 symmetry, EGB, electrochemical oxidation, homocoupling