Details

Autor(en) / Beteiligte

• Ghigo, Giovanni
• Bonomo, Matteo
• Antenucci, Achille
• Damin, Alessandro
• Dughera, Stefano

Titel

Ullmann homocoupling of arenediazonium salts in a deep eutectic solvent. Synthetic and mechanistic aspects

Ist Teil von

• RSC advances, 2022-09, Vol.12 (41), p.2664-26647

Ort / Verlag

England: Royal Society of Chemistry

Erscheinungsjahr

2022

Quelle

EZB Electronic Journals Library

Beschreibungen/Notizen

• A deep eutectic solvent (DES) based on glycerol and KF is successfully exploited as a solvent medium in Ullmann homocoupling of arenediazonium salts. The reactions were carried out in mild conditions and target products were obtained in fairly good yields. A computational study is presented aiming to understand the reaction mechanism and Raman spectroscopy is employed as an experimental tool to support it. DES is exploited as a solvent media in Ullmann homocoupling of arenediazonium salts. Computational study supported by Raman spectroscopy is presented, aiming to elucidate the reaction mechanism.