Details

Autor(en) / Beteiligte

• Yu, Zhi-Cheng
• Zhou, You
• Chen, Xiang-Long
• Ma, Jin-Tian
• Wang, Li-Sheng
• Wu, Yan-Dong
• Wu, An-Xin

Titel

One-Pot Synthesis of Diaryl 1,2-Diketones via Zn-Mediated Reductive Coupling

Ist Teil von

• Journal of organic chemistry, 2022-11, Vol.87 (21), p.14037-14044

Ort / Verlag

United States: American Chemical Society

Erscheinungsjahr

2022

Quelle

MEDLINE

Beschreibungen/Notizen

• A reductive coupling reaction was established for the synthesis of diaryl 1,2-dicarbonyl compounds from aryl methyl ketones in good yields. The mechanistic study showed the reaction undergoes C­(CO)–C­(sp3) bond cleavage, with the reductive coupling reaction occurring through an electron transfer process. Notably, the reaction not only is simple to operate but also has mild reaction conditions and a wide range of applicable substrates.