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Long‐Range Interactions in Diatomic Catalysts Boosting Electrocatalysis
Ist Teil von
Angewandte Chemie International Edition, 2022-12, Vol.61 (52), p.e202213318-n/a
Auflage
International ed. in English
Ort / Verlag
Germany: Wiley Subscription Services, Inc
Erscheinungsjahr
2022
Quelle
Alma/SFX Local Collection
Beschreibungen/Notizen
The simultaneous presence of two active metal centres in diatomic catalysts (DACs) leads to the occurrence of specific interactions between active sites. Such interactions, referred to as long‐range interactions (LRIs), play an important role in determining the rate and selectivity of a reaction. The optimal combination of metal centres must be determined to achieve the targeted efficiency. To date, various types of DACs have been synthesised and applied in electrochemistry. However, LRIs have not been systematically summarised. Herein, the regulation, mechanism, and electrocatalytic applications of LRIs are comprehensively summarised and discussed. In addition to the basic information above, the challenges, opportunities, and future development of LRIs in DACs are proposed in order to present an overall view and reference for future research.
Diatomic catalysts have attracted much attention, especially in electrochemistry. However, there have been no comprehensive reviews on long‐range interactions (LRIs) between metallic centres. This Minireview introduces the key aspects of LRIs and highlights opportunities for regulating electrocatalytic mechanisms, thus presenting guidelines for the targeted usage of LRIs.