Details

Autor(en) / Beteiligte

• Li, Wen‐Hao
• Yang, Jiarui
• Wang, Dingsheng

Titel

Long‐Range Interactions in Diatomic Catalysts Boosting Electrocatalysis

Ist Teil von

• Angewandte Chemie International Edition, 2022-12, Vol.61 (52), p.e202213318-n/a

Auflage

International ed. in English

Ort / Verlag

Germany: Wiley Subscription Services, Inc

Erscheinungsjahr

2022

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• The simultaneous presence of two active metal centres in diatomic catalysts (DACs) leads to the occurrence of specific interactions between active sites. Such interactions, referred to as long‐range interactions (LRIs), play an important role in determining the rate and selectivity of a reaction. The optimal combination of metal centres must be determined to achieve the targeted efficiency. To date, various types of DACs have been synthesised and applied in electrochemistry. However, LRIs have not been systematically summarised. Herein, the regulation, mechanism, and electrocatalytic applications of LRIs are comprehensively summarised and discussed. In addition to the basic information above, the challenges, opportunities, and future development of LRIs in DACs are proposed in order to present an overall view and reference for future research. Diatomic catalysts have attracted much attention, especially in electrochemistry. However, there have been no comprehensive reviews on long‐range interactions (LRIs) between metallic centres. This Minireview introduces the key aspects of LRIs and highlights opportunities for regulating electrocatalytic mechanisms, thus presenting guidelines for the targeted usage of LRIs.