Details

Autor(en) / Beteiligte

• Bicalho, Hudson A
• Saraci, Felix
• Velazquez-Garcia, Jose de J
• Titi, Hatem M
• Howarth, Ashlee J

Titel

Unravelling the synthesis of a rare-earth cluster-based metal-organic framework with spn topology

Ist Teil von

• Chemical communications (Cambridge, England), 2022-09, Vol.58 (78), p.1925-1928

Ort / Verlag

Cambridge: Royal Society of Chemistry

Erscheinungsjahr

2022

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Y-CU-45, an analogue of Zr-MOF-808, is synthesized for the first time. Several reaction conditions are tested demonstrating that two fluorinated modulators are required for a reproducible synthesis yielding high quality material. Y-CU-45 shows high crystallinity and surface area, shining light on the potential for rare-earth cluster-based MOFs with open metal sites. A novel rare-earth analogue of MOF-808 with 6-connected nodes is synthesized, shining light on the potential for open metal sites in rare-earth cluster-based MOFs.